DECLARE @xml xml
SET @xml = ' <Root> <Item>one</Item> <Item>two</Item> <Item>three</Item> <Item>four</Item> <Item>five</Item> </Root> '
SELECT Temp.Items.value('.','varchar(16)') AS [Items] FROM @xml.nodes('//Item') AS Temp(Items)
/* For general information, see “Introduction to XQuery in SQL Server 2005” http://technet.microsoft.com/en-us/library/ms345122.aspx */